Solids at the liquid–liquid interface: Electrocatalysis with pre-formed nanoparticles

Wave Propagation at an Interface of Elastic and Microstretch Thermoelastic Solids with Microtemperatures

In the present paper, the problem of reflection and transmission of waves at an interface of elastic and microstretch thermoelastic solids with microtemperatureshas been studied. The amplitude ratios of various reflected and transmitted waves are functions of angle of incidence and frequency of incident wave. The expressions of amplitude ratios have been computed numerically for a particular mo...

Interface waves in pre-stressed incompressible solids

We study incremental wave propagation for what is seemingly the simplest boundary value problem, namely that constitued by the plane interface of a semi-infinite solid. With a view to model loaded elastomers and soft tissues, we focus on incompressible solids, subjected to large homogeneous static deformations. The resulting strain-induced anisotropy complicates matters for the incremental boun...

Mixed Adsorption Layers Formed at the Electrode – Solution Interface

Evidence for the formation of dynamically created pre-formed ions at the interface of isotopically enriched thin films.

A novel approach to elucidate the ionization mechanism for the [M + H]+ molecular ion of organic molecules is investigated by molecular depth profiling of isotopically enriched thin films. Using a model bi-layer film of phenylalanine (PHE) and PHE-D8, the results show formation of an [M + D]+ molecular ion for the non-enriched PHE molecule attributed to rearrangements of chemical damage due to ...

Scanning Electrochemical Microscopy. 31. Application of SECM to the Study of Charge Transfer Processes at the LiquidLiquid Interface

The kinetics of the electron transfer and ion transfer at the interface between two immiscible electrolyte solutions (ITIES) were probed directly by scanning electrochemical microscopy (SECM). The liquid/liquid (Le., waterhitrobenzene) interface appeared to be sharp and wave-free on the submicrometer scale. The use of SECM allowed the electron transfer between ferrocene species in nitrobenzene ...